Catalyst N° 022 of 125 4 Apr 2024
Understanding the growing world of battery recycling
with Dan Steingart, chair of the earth and environmental engineering department, Columbia University
In this note
The question
Battery recycling is technically well understood, so why is it such a hard business, and what would a recycler have to do to make it work?
The answer
Because a recycler’s customer is also its supplier. Steingart’s view is that the primary processes are a cost center, high capital cost and low margin, and that whoever shakes out as the winner will face enormous margin pressure regardless of how good their chemistry is. The escape routes are owning the feedstock or being built into battery manufacturing from the start. On top of that, all of today’s US recyclers run on manufacturing scrap, which the gigafactories are trying to eliminate, while end-of-life batteries are deliberately slow to arrive, so a lean period sits between the two.
03The argument
The process is worth understanding mostly in order to see that it is not the differentiator. Packs arrive welded, with designs that vary by manufacturer, and have to be opened without breaching the cells inside, of which a Tesla pack holds something over 8,000. The cells carry unknown residual charge and, as they age or get fast-charged, accumulate what Steingart calls zombie lithium, metallic lithium deposited where a lithium-ion cell is not supposed to have any, which is a live hazard for whoever shreds it. After shredding you have black mass, and from there the two options are both inherited wholesale from ore processing. Pyrometallurgy burns it: cheap per unit and a guaranteed result, but capital heavy and with off-gassing nasty enough that the US has essentially stopped building smelters, while it remains, as Steingart understands it, the majority of recycling worldwide and common in China and India. Hydrometallurgy digests it in acid instead, and the trick that makes it practical for batteries is piranha solution, sulfuric acid with hydrogen peroxide, which cuts residence time from the roughly 90 days a copper leach pile needs down to hours and moves the whole operation into a closed reactor in a warehouse. Western recyclers are hydrometallurgical almost across the board.
Within that there is a real technical disagreement, and Steingart flags it as his own minority position. After digestion you can swing pH upward with sodium hydroxide and precipitate metals out in sequence, which is cheapest and needs fewer reactors, but is imperfect because metals mix in solution. Or you can use solvent extraction, where organic ligands are designed to grab specific metals and can be chained into circuits. Steingart prefers it, arguing from copper that the operating cost is far lower once it is running: a mine he visited in Morenci, Arizona needed crews walking miles of extraction loops twenty years ago and on a recent visit ran nearly unattended with daily pH checks. He is explicit that this is his experience rather than a settled result, and invites listeners to come at him with knives.
None of that decides who wins, which is the turn in the episode. The three large US players he takes on are three postures toward one hydrometallurgical base. Redwood Materials, on his reading, wants to be the mine of the future, on the view that the value is in controlling the input material rather than the process, because any downstream product faces margin pressure from battery makers who are themselves squeezed by their automaker customers. Ascend Elements innovates downstream instead, with a hydro-to-cathode process that deliberately skips separating the metals on the reasoning that the cathode you want looks a lot like the cathode coming in, needing mainly a nickel top-up as chemistries shift. Li-Cycle he calls the realpolitik of the three, coming from Hatch’s extraction equipment lineage and aiming simply to make the metal sulfates cathode manufacturers already know how to buy. But all three live on gigafactory scrap, which he understands to run over 20% of production, and that is the trap. Manufacturers have every incentive to drive scrap toward zero because it is pure waste, and we simultaneously want batteries to last as long as possible, so the end-of-life stream is deliberately slow in arriving. The two curves leave a gap, and every recycler has to survive it.
What happens after the gap closes is not obviously better. Automakers will want to control their own material, Tesla largely does already, and the others will follow as their fleets age, which leaves recyclers as tollers: paid to process somebody else’s material, competing on process efficiency alone. In a reasonably efficient market, an advance that lowers recycling cost buys a year or two of extra profit before the market prices it away, and the pressure for cheaper batteries guarantees it will. This also answers a question Steingart says he asked himself: why the big miners are not seriously in this. Their value sits in what they own in the ground, and their processing exists to monetize that; in recycling, the feedstock is either factory scrap or somebody else’s product, so there is nothing for them to own. Chemistry is making it harder rather than easier, because the output has to beat a benchmark metal price and the industry has swung back toward lithium iron phosphate, where lithium is the only comfortably valuable component, phosphorus has little recycled value today, and conventional digestion barely makes sense. The one opening he sees there is direct recycling, refurbishing the cathode rather than breaking it down, which suits lithium iron phosphate because the material changes little as it cycles. He notes in the same breath that he is publicly skeptical of direct recycling and thinks it is a bad idea for nickel chemistries, where breaking material down to sulfates and rebuilding is cheaper and safer.
04What you need to know first
- Black mass
- What you get after shredding cells: a homogenized mix of the valuable materials, and the common starting point for both recycling routes.
- Pyrometallurgy and hydrometallurgy
- Heat versus acid. Smelting the material down, or dissolving it and pulling metals back out of solution. Both are borrowed directly from how ore is processed.
- NMC and LFP
- The two dominant cathode chemistries: nickel-manganese-cobalt, which is denser and contains expensive metals, and lithium iron phosphate, which is cheaper and safer with lower energy density. The economics of recycling turn almost entirely on which one is in the cell.
- Tolling
- Processing material you do not own, for a fee, and handing it back. It caps what a business can earn regardless of how well it runs, which is Steingart’s core worry about the industry.
05Details worth keeping
- Second-life uses for recovered cells sound appealing and Steingart is unconvinced. His lab does this work and he says grading cells is hard to justify on cost, that it is not a bankable effort yet, and that even with perfect measurement he is unsure the cells belong in those applications.
- Piranha solution eats through almost anything and handling it is a real challenge, but it is what lets hydrometallurgy happen in a warehouse instead of a leach pit, with no local contamination if the waste is handled properly.
- Steingart limits his company comments to the three whose flow sheets and patents he has read, notes there are many others, and estimates China alone has 50 to 100 recyclers at different points in the stack.
- Nickel drove most of the deal flow in 2021 through 2023 and prices have since crashed. He points out the industry has done this before: nickel prices pushed the world toward lithium iron phosphate around 2009-10, crashed in the early 2010s and brought nickel chemistries back, then spiked and swung it to lithium iron phosphate again.
- On anodes, graphite recycling is in its infancy and hard to justify. Carbon is not as forgiving as metal, since you cannot simply break it down and rebuild the structure, small differences in starting graphite have large performance effects, and there is plenty of graphite in the ground. Silicon is easier, since spent silicon can be processed back to silane and silane is the expensive step, though there is no shortage of silica either. Lithium is the exception and should be recovered at close to 100%.
- Northvolt, which funds his lab, treats recycling as part of the manufacturing process from the beginning rather than a separate industry. He offers this as one of the two structures that could work.
- Kann came into the conversation with the view that recycling capacity is headed for large oversupply relative to available batteries, and says listeners correctly pushed back that not all capacity is equal, which is why the episode covers the technology at all.
06Claims worth citing
All figures as stated on 2024-04-04 and attributed to the speaker. Metal prices and scrap rates in particular were moving at the time, and several company details are described as Steingart’s reading of public materials rather than inside knowledge.
- Gigafactory scrap is currently exceptionally high, over 20%, and is the main feedstock for all three large US recyclers. Hedged as “as I understand it.” Steingart
- A Tesla pack contains something over 8,000 cells. Steingart
- Copper leach piles have a residence time on the order of three months; piranha solution cuts digestion from about 90 days to a few hours. Steingart
- Pyrometallurgy is, as he understands it from conversations with Chinese recyclers, currently the majority of recycling methods, though not in the US. Steingart
- China has roughly 50 to 100 battery recyclers at different points in the tech stack. Steingart
- A recycler has to beat the exchange price for its eventual sulfate to be competitive. The transcript garbles the benchmark, rendering the London Metal Exchange as “LMX” and naming Alibaba as an alternative reference price, so the precise benchmark is unclear even though the principle is not. Steingart
- Of the three anode materials, carbon most likely will not be recycled any time soon, silicon has some merit, and all the lithium in cells should be recycled to nearly 100%. Steingart
- Most silane production is in China and Korea, with a couple of facilities in the far northwest of the US. Steingart
- Unit economics of lithium iron phosphate recycling were worked out in painful detail around 2016 by Rebecca Ciez and Jay Whitacre, which Steingart calls prescient. Ciez and Whitacre, cited by Steingart
07Where it’s contested
- Solvent extraction is his own minority view. He says precipitation is cheaper on capital and dominant in 2024, argues solvent extraction has much lower operating cost based on his copper experience, acknowledges he is in the minority, and invites listeners to come at him with knives.
- He is skeptical of direct recycling and still thinks it is lithium iron phosphate’s only viable route. He says people who know him would do a spit take hearing him endorse it, and holds that for nickel chemistries it is genuinely difficult and that breaking material down and rebuilding is cheaper and safer.
- Company details are read off public materials. He confines himself to three companies whose flow sheets and patents he has seen, and when Kann says Redwood is also going all the way downstream to cathode, Steingart answers that he thinks so but does not know.
- He disclaims operating experience. He describes himself as a process engineer and professor who has never had to be responsible for producing this material, and says he does not want to be read as underestimating how hard recycling is.
- He wants to be wrong. Asked to confirm Kann’s summary that he is pro-recycling but skeptical of the business, he agrees, then says recycling has to happen, would happen faster if the economics were better, and that he would love to be proven wrong on them.
- The funding relationship is disclosed in the same answer in which Northvolt’s integrated model is praised. Stated plainly on air and normal for academic work; worth noting only so the endorsement is read as an informed opinion rather than a disinterested one.